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Pharm Sci. 2019;25(3): 244-253. doi: 10.15171/PS.2019.31

Research Article

Performance of Local Composition Models to Correlate the Aqueous Solubility of Naproxen in Some Choline Based Deep Eutectic Solvents at T = (298.15-313.15) K

Masumeh Mokhtarpour 1, Hemayat Shekaari 1 * ORCID, Fleming Martinez 2 ORCID, Mohammed Taghi Zafarani-Moattar 1

Cited by CrossRef: 15

1- Azad H, Shekaari H, Ghaffari F, Mokhtarpour M, Hokm Abad M. Study of fluconazole drug behavior in deep eutectic solvents: thermodynamic properties, solubility measurement, and fluorescence spectroscopy. RSC Adv. 2025;15(14):11194 [Crossref]
2- Cysewski P, Jeliński T, Kukwa O, Przybyłek M. From Molecular Interactions to Solubility in Deep Eutectic Solvents: Exploring Flufenamic Acid in Choline-Chloride- and Menthol-Based Systems. Molecules. 2025;30(16):3434 [Crossref]
3- Abdkarimi F, Haghtalab A. Solubility measurement and thermodynamic modeling of sertraline hydrochloride and clopidogrel bisulfate in deep eutectic solvent of choline chloride and malonic acid. Journal of Molecular Liquids. 2021;344:117940 [Crossref]
4- Zarei A, Haghbakhsh R, Raeissi S. Overview and thermodynamic modelling of deep eutectic solvents as co-solvents to enhance drug solubilities in water. European Journal of Pharmaceutics and Biopharmaceutics. 2023;193:1 [Crossref]
5- Khorsandi M, Shekaari H, Mokhtarpour M. Measurement and correlation of coumarin solubility in aqueous solution of acidic deep eutectic solvents based on choline chloride. Fluid Phase Equilibria. 2020;524:112788 [Crossref]
6- Khodadadi A, Boghrat S, Besharati Z, Hashemi S. The impact of solvent composition, concentration, and temperature on the solubility of naproxen: A review of mono-solvent, binary, and ternary systems. Journal of Holistic Integrative Pharmacy. 2025;6(4):427 [Crossref]
7- Khorsandi M, Nemati-Kande E, Hosseini F, Martinez F, Shekaari H, Mokhtarpour M. Effect of choline chloride based deep eutectic solvents on the aqueous solubility of 4-hydroxycoumarin drug: Measurement and correlation. Journal of Molecular Liquids. 2022;368:120650 [Crossref]
8- Patidar P, Kanoje B, Bahadur A, Kuperkar K, Ray D, Aswal V, Wang M, Chen L, Bahadur P. Micellar characteristics of an amphiphilic star-block copolymer in DES-water mixture. Colloid Polym Sci. 2021;299(1):117 [Crossref]
9- Barzegar-Jalali M, Jafari P, Jouyban A. Experimental determination and correlation of naproxen solubility in biodegradable low-toxic betaine-based deep eutectic solvents and water mixtures at 293.15 K to 313.15 K. Fluid Phase Equilibria. 2022;560:113508 [Crossref]
10- Golgoun S, Mokhtarpour M, Shekaari H. Solubility Enhancement of Betamethasone, Meloxicam and Piroxicam by Use of Choline-Based Deep Eutectic Solvents . Pharm Sci. 2020;27(1):86 [Crossref]
11- Shekaari H, Mokhtarpour M, Mokhtarpour F, Faraji S, Martinez F, Zafarani-Moattar M. Significant Increase in the Solubility of Celecoxib in Presence of Some Deep Eutectic Solvents as Novel Sustainable Solvents and the Thermodynamic Analysis of These Systems. Pharm Sci. 2020;26(4):423 [Crossref]
12- Sayad T, Poturcu K, Moradi M, Rahimpour E, Zhao H, Jouyban A. Solubility study of carvedilol in the aqueous mixtures of a choline chloride/propylene glycol deep eutectic solvent. Journal of Molecular Liquids. 2021;342:117537 [Crossref]
13- Khorsandi M, Shekaari H, Mokhtarpour M, Gondoghdi P, Hamishehkar H. Molecular interactions, solubility, and cytotoxic activity of 4‑hydroxycoumarin in choline chloride‑based acidic deep eutectic solvents. Sci Rep. 2026;16(1) [Crossref]
14- Besharati Z, Hashemi S, Babapoor A, Seyfaee A. Prediction of Naproxen Solubility at Various Temperatures and Concentrations using Machine Learning Approaches. Chemistry Africa. 2025;8(6):2369 [Crossref]
15- Ali Z, Yadav P, Tiwari A, Dixit S, Panday V, Patel D. The revolution of deep eutectic solvents and natural deep eutectic solvents in pharmaceutical and metal recovery industries: beyond solvents—a review. Journal of Molecular Liquids. 2026;457:129768 [Crossref]
16- Rodríguez-Juan E, López S, Abia R, J. G. Muriana F, Fernández-Bolaños J, García-Borrego A. Antimicrobial activity on phytopathogenic bacteria and yeast, cytotoxicity and solubilizing capacity of deep eutectic solvents. Journal of Molecular Liquids. 2021;337:116343 [Crossref]
17- Huang X, Dong W, Luo X, Xu L, Yang D, Wang Y. Low-melting mixture solvents as novel solubilizing agents: Improving tolvaptan formulation and therapeutic efficacy. Journal of Molecular Liquids. 2024;414:126179 [Crossref]
18- Khorsandi M, Shekaari H, Mokhtarpour M, Hamishehkar H. Cytotoxicity of some choline-based deep eutectic solvents and their effect on solubility of coumarin drug. European Journal of Pharmaceutical Sciences. 2021;167:106022 [Crossref]
19- Abad M, Shekaari H, Janbezar E, Ghasemzadeh S. Effects of some surface active ionic liquids on the aqueous solubility, thermodynamic properties and fluorescence behavior of drug diclofenac sodium. Sci Rep. 2026;16(1) [Crossref]
20- Zendehbad A, Bagheri M, Mokhtarpour M, Shekaari H, Zafarani-Moattar M. Effect of Ionic Liquid Choline Lactate on Thermodynamic and Transport Properties of Amino Acids Glycine, l-Alanine, and l-Phenylalanine. J Chem Eng Data. 2024;69(7):2528 [Crossref]
21- El Masri S, Ruellan S, Zakhour M, Auezova L, Fourmentin S. Cyclodextrin-based low melting mixtures as a solubilizing vehicle: Application to non-steroidal anti-inflammatory drugs. Journal of Molecular Liquids. 2022;353:118827 [Crossref]
22- Soltanmohammadi F, Jouyban A, Shayanfar A. New aspects of deep eutectic solvents: extraction, pharmaceutical applications, as catalyst and gas capture. Chem Pap. 2021;75(2):439 [Crossref]

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