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Pharm Sci. 2021;27(Suppl 1): S109-S121.
doi: 10.34172/PS.2021.3

Scopus ID: 85118951907
  Abstract View: 2383
  PDF Download: 919

COVID-19

Research Article

Molecular Docking and Dynamics Simulations Reveal the Potential of Anti-HCV Drugs to Inhibit COVID-19 Main Protease

Ahmed Ali Al-Karmalawy 1* ORCID logo, Radwan Alnajjar 2,3, Mohammed Dahab 4, Ahmed Metwaly 5, Ibrahim Eissa 4

1 Department of Pharmaceutical Medicinal Chemistry, Faculty of Pharmacy, Horus University -Egypt, New Damietta 34518, Egypt.
2 Department of Chemistry, Faculty of Science, University of Benghazi, Benghazi, Libya.
3 Department of Chemistry, University of Cape Town, Rondebosch 7701, South Africa.
4 Pharmaceutical Medicinal Chemistry and Drug Design Department, Faculty of Pharmacy (Boys), Al-Azhar University, Cairo11884, Egypt.
5 Pharmacognosy Department, Faculty of Pharmacy (Boys), Al-Azhar University, Cairo 11884, Egypt.
*Corresponding Author: Email: akarmalawy@horus.edu.eg

Abstract

Background: Drug repurposing is the fastest effective method to provide treatment for coronavirus disease (COVID-19). Drugs that targeting a closely related virus with similar genetic material such as hepatitis C virus (HCV) and more specifically targeting a similar viral protease would be an excellent choice.

Methods: In this study, we carried out a virtual screening for fifteen anti HCV drugs againstCOVID-19 main protease using computational molecular docking techniques. Moreover, Velpatasvir (4) and Sofosbuvir (13) drugs were further evaluated through molecular dynamics simulations followed by calculating the binding free energy using the molecular mechanics generalised born/solvent accessibility (MM-GBSA) approach.

Results: The binding affinity descending order was N3 natural inhibitor (1), Velpatasvir (4),Sofosbuvir (13), Ombitasvir (3), Glecaprevir (2), Asunaprevir (8), Paritaprevir (10), Grazoprevir(11), Elbasvir (6), Ledipasvir (5), Daclatasvir (7), Pibrentasvir (9), Simeprevir (12), Dasabuvir(14), Taribavirin (16) and finally Ribavirin (15). Molecular dynamics simulation reveals that sofosbuvir (13) has exciting properties and it was stable within the active site and also showed good MM-GBSA compared to the natural inhibitor N3.

Conclusion: Our results could be auspicious for fast repurposing of the examined drugs either alone or in combinations with each other for the treatment of the COVID-19. Furthermore, this work provides a clear spot on the structure-activity relationship (SAR) for targeting the severe acute respiratory syndrome coronavirus 2 (SARS-CoV-2) main protease and helps the design and synthesis of new drugs in the future targeting it as well.

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Submitted: 10 Nov 2020
Revision: 31 Dec 2020
Accepted: 01 Jan 2021
ePublished: 29 Jan 2021
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